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71.
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Non‐Invasive Salivary Electrochemical Quantification of Paraquat Poisoning Using Boron Doped Diamond Electrode 下载免费PDF全文
Thiago Matheus Guimarães Selva William Reis de Araujo Thiago Regis Longo Cesar da Paixão 《Electroanalysis》2015,27(7):1642-1648
The present work describes the first electrochemical method for quantifying paraquat herbicide poisoning in human saliva samples. Paraquat shows two couples of well‐defined peaks in aqueous solution using a boron doped diamond (BDD) electrode. By using square wave voltammetry (SWV) technique under optimum experimental conditions, a linear analytical curve was obtained for paraquat concentrations ranging from 0.800 to 167 µmol L?1, with a detection limit of 70 nmol L?1. This method was applied to quantify paraquat spikes in human saliva samples and in two different water samples (tap and river). The recovery values obtained ranged from 83.0 to 104 % and 99.1 to 105 %, respectively, which highlight the accuracy of the proposed method. 相似文献
74.
A Nitrite Electrochemical Sensor Based on Boron‐Doped Diamond Planar Electrochemical Microcells Modified with a Monolacunary Silicotungstate Polyoxoanion 下载免费PDF全文
Yosra Sahraoui Amel Sbartai Sana Chaliaa Abderrazak Maaref Amor Haddad Nicole Jaffrezic‐Renault 《Electroanalysis》2015,27(6):1359-1367
A new boron doped diamond microcells (BDD) was modified, for rapid, selective and highly sensitive determination of nitrite, using a coating film of polyoxometalates (POMs), formed by cyclic voltammetry on the molecular p‐phenylenediamine (PPD) functionalized BDD. The scanning electron microscopy (SEM) technique was used to examine the morphology of (PPD/SiW11) modified (BDD) electrode. It was found that (SiW11) layer was uniformly formed on the electrode surface. It was observed that (BDD/PPD/SiW11) showed excellent electrocatalytic activities towards nitrite ion. Under the selected conditions, the anodic peak maximum at ?0.6 V was linear versus nitrite concentration in the 40 µM–4 mM range, and the detection limit obtained was 20 µM. The newly developed electrode has been successfully applied to the determination of nitrite content in real river water samples. 相似文献
75.
Under the influence of previously published and some new theoretical results, potential‐ dependent adsorption and desorption of model electroinactive surfactants Triton X‐100 (T‐X‐100 or polyethylene glycol p‐(1,1,3,3‐tetramethylbutyl)‐phenyl ether) and sodium dodecyl sulfate (SDS) on the static mercury drop electrode (SMDE) were studied by square‐wave voltammetry (SWV). Although (according to the theory) the resulting current – potential curve should consist of two highly separated peaks, only desorption signal could be seen on each experimentally obtained voltammogram, most probably because of the limitations concerning the available potential range. Different properties of the recorded peak are in good agreement with the theory indicating that square‐wave voltammetry could be treated as a potential tool for tensammetric studies of electroinactive surface active substances. 相似文献
76.
77.
B. Visser M. Beck P. Bornhauser G. Knopp T. Gerber R. Abela J. A. van Bokhoven P. P. Radi 《Journal of Raman spectroscopy : JRS》2016,47(4):425-431
The potential of two‐color resonant and degenerate four‐wave mixing spectroscopy for investigations of the complex spectra of transition metal dimers is explored. Two‐color resonant and degenerate four‐wave mixing spectroscopy scans of the well‐known A‐X and B‐X transitions in Cu2 are reported and compared with previous experimental data obtained from standard single‐resonance techniques. The selectivity of the method is shown to enable the measurement of isotopologue pure spectra without the need for isotopically enriched metal targets. Specific subsets of the rovibronic structure are separated in a congested spectral region of overlapping transitions. The sensitivity of the method compares satisfactorily with linear spectroscopic methods such as laser‐induced fluorescence and cavity ring‐down. A new laser vaporization source for the production of transition metal dimers and clusters has been constructed. The new design aims for a high number density and maximum possible shot‐to‐shot stability. The possibilities of further applications of non‐linear four‐wave mixing spectroscopy to Cu2 and other transition metal dimers are discussed. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
78.
促进其线性频散特征另一种形式的Bousinesq方程 总被引:5,自引:1,他引:5
Bousinesq方程能够用于模拟表面重力波传播过程中的折射、绕射、反射以及浅化,非线性作用等现象.用不同垂直积分方法所得到的二维Boussinesq方程形式具有不同的线性频散特征.采用两个不同的水深层的水平速度变量组合,推导出一个新形式的Bousinesq方程.通过对其参数的设置可得到精确的线性频散解Pade近似4阶精度.其适用范围已由原来的浅水,向深水拓进.相速误差小于2%,其拓展适用范围可达到08个波长水深.应用所得到的新型Bousinesq方程,采用有限差分法,对经典工况进行了数值模拟,其计算结果表明,计算值与物模实验值吻合较好.这说明本文新形式的Boussinesq方程对变水深非线性效应所产生的能量频散有着较为精确的描述 相似文献
79.
The motion of fragments following disintegration of a meteoroid during its flight through the Earth's atmosphere is investiated.
Shock wave configurations, aerodynamical forces and moments acting on each fragment and the trajectories of the pieces are
determined for hypothetical initial configurations. The results of numerical simulations show that a meteoroid's breakup may
lead to both increase and decrease of the total cross section, drag forces and energy release in the atmosphere. As a consequence
the emitted radiation varies. 相似文献
80.
The paper studies the relationship between the physical characteristics of a cylinder and the properties of normal axisymmetric waves in elastic–liquid waveguides. The cylinder is made of a compliant material in which the velocity of shear waves is less than the sonic velocity in a perfect compressible liquid. The complete system of dynamic elasticity equations and the wave equation are used to describe the wave fields in the elastic cylinder and fluid, respectively. This approach allows obtaining the dispersion characteristics of coupled normal waves in compound waveguides over wide ranges of frequencies and wavelengths. The curves of real, imaginary, and complex wave numbers versus frequency are plotted for specific pairs of waveguide materials. Computations are carried out for a thick-walled cylinder filled with a fluid and immersed in either vacuum or a fluid. It is found out that compliant and rigid materials of the cylinder affect differently the wave interaction process in elastic–liquid waveguides 相似文献